Ethanol
has the potential of significantly reducing the United States
dependence on foreign oil. From every barrel of oil (40
gals) approximately 20 gallons of gasoline is produced.
Modern automobiles can burn a mixture of gasoline ranging
between 12% and 85% ethanol combined with 88% gasoline and
15% gasoline, E-12 and E-85.
Currently there are approximately 7.5 billion gallons of
ethanol produced in the United States a year. Over 99% of
this ethanol uses corn grain as the starting material.
Pan Gen Global has a US patent
that can use cellulose (woody portion of all plant life)
to produce ethanol; the starting materials for our process
are rice straw and rice hulls, and in the future corn
stover and cobs, wheat straw and husks, wood chips from
forest slashing, and sawdust from saw mills. How much ethanol
can be produced from these cellulose-based raw materials?
Using 2003 farm data from the US Department of Agriculture
and taking into consideration the availability of these
cellulose based materials, it has been conservatively estimated
that over 1.0 trillion gallons of ethanol could be produced
per year. This would reduce the importation of oil by an
estimated 75%. Pan Gen Global will initially
build a 130,000 ton/yr rice straw plant near Colusa, CA.
This plant will produce 12.5 million gallons of fuel ethanol,
16,800 tons of silica products, commercial carbon dioxide,
and a high energy lignin fuel that will be used internally
in the plant to reduce the cost of natural gas.
Comparisons between our system and traditional spiral wound
membrane systems
A spiral wound membrane, both RO and UF; this increases
the surface area of the membrane winding a membrane/separator
system into the shape of a star. Due to the membrane/separator
proximities spiral wound membranes are “plugged”
by particulate matter in the feed liquid.
The Pan Gen Global system differs from the spiral wound systems by
placing the membrane directly in contact with the feed liquid
and pumping this feed liquid at a high flow rate. This flow
rate acts to “sweep” the membrane and prevents
“plugging.”
The niche that Pan Gen Global's system can fill is its ability to filter
thixotropic (viscous) Newtonian and non-Newtonian liquids.
For example, our UF system can take tomato juice (Newtonian
liquid) and by removing the water, produce tomato paste
(non-Newtonian liquid.)
Our ultrafiltration (UF) can be cast to do total rejection
of 5,000 to 20,000 molecular weight (MW) molecules. For
example, large molecules (lignin), enzymes, bacteria, lactose,
colloidal matter, fine suspended particulate matter, and
proteins will not pass through the membrane.
We claim:
A method for producing lignin fuel, silica/sodium oxide,
cellulose, and cellulose derivatives from plant biomass
comprising the steps of placing the plant biomass in a hammermill
or ball mill and grinding the plant biomass to 45 to 55
mesh, feeding the reduced size biomass into the first counter-current
extractor, admixing the biomass with a mild acid solvent
solution of acetic, carbonic, hydrochloric, phosphoric,
or sulfuric acid at a temperature between 40 and 60 degrees
C. and a residence time between 50 and 70 minutes, withdrawing
a solvent stream from the first counter-current extractor
containing 5-carbon sugars, soluble plant proteins, and
soluble polypeptides which is passed to a fermentation tank
where the 5-carbon sugars are fermented to ethanol,
withdrawing a solid material stream from the first counter-current
extractor and passing the solid material through a belt-press
filter, dewatering the solid material to between 70% and
80% total solids, and feeding the dewatered solid material
stream into a second counter-current extractor, admixing
the solid material with a caustic hydroxide solution, dissolving
the lignin and silica,
withdrawing a solvent stream from the second counter-current
extractor containing the lignin and caustic silicate and
passing the solvent to an ultrafiltration membrane system,
separating and concentrating the lignin from the solvent
containing the caustic solution,
withdrawing from the ultrafiltration membrane unit a caustic
silicate solution whereby a silica caustic oxide solution
is produced,
withdrawing between 10% and 20% of the caustic silicate
solution from the ultrafiltration membrane unit and sending
the caustic silicate solution to the caustic solvent added
to the second counter-current extractor as a feed-back solvent,
withdrawing the solid stream from the second counter-current
extractor and passing the solid stream to a washing centrifuge
and passing the solid to a belt-press filter dewatering
the solid to 75% total solids,
withdrawing the solid from the belt-press filter and passing
the solid to a tank wherein the solid cellulose material
is converted to a glucose steam using acid hydrolyzing enzymes,
Silica Uses in Industry
Abrasive Wheels
Absorbents
Adhesives
Asbestos Products
Bar Soap
Beater Sizing Paper
Bleaching Textiles and Paper
Boiler Compounds
Brick-Making
Briquetting
Coal
Glass
Ores
Buffering Agents
Building Materials
Cements
Ceramics
Cement Grouts
Chemical Grouting
Cleaning Compounds
Coagulant
Coatings
Enamel
Roofing Granules
Welding Rods
Concrete Cleaners
Concrete Treatment
Corrosion Control
Corrugated Board
Dairy Cleaners
Deflocculating of Clays
Dehumidifiers
De-inking Paper
Detergent Formulations
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Dishwashing
Oil Drilling Fluids
Mud Additive
Silicate Base Mud
Synthetic Mud
Drum Washing
Earthwork Construction
Egg Washing
Fiber Drums
Fire resistant paint
Floor cleaners
Fly Ash Structural Materials
Foil laminating
Foundry
Cores
Hot Topes
Molds
Frits
Fruit & Vegetable Peeling
Ground Water Control
Heavy Duty Cleaning
Hog Scalding
Laminating Metal Foil
Laundry Operations
Leather Processing
Liquid Detergent
Lithographic Printing
Magnesium Trisilicate
Metal Cleaning
Molecular Sieves
Oil Refining
Oil Reclaiming
Ore Flotation
Paint & Rubber Fillers |
Paints
Paper Coating
Paper Tube Winding
Pigments
Polishing Wheel Cement
Portland Cement
Poultry Processing
Radiator Compounds
Release Agent
Rust Remover
Sealing Containers
Scaling Metal Castings
Secondary Oil Recovery
Silica Gel
Aerogel
Hydrogel
Xerogel
Soap Conditioners
Soap-Making
Solid Fiberboard
Space Vehicle Paint
Steam Cleaning
Synthetic Catalysts
Synthetic Detergents
Textile Processing
Timed Fertilizers
Tire Cleaners
Titanium Dioxide
Ultramarine
Vegetable Oil Refining
Washing Locomotives
Water Clarification
Water Treatment
Wire Drawing
Zeolite (Synthetic) |
The largest industrial uses of Silica/Sodium Oxide (Sodium
Silicate) are in the Paper Industry; the Pap Products (de-inking, paper
tubes, etc.); Detergent & Soap producers, Producers
of Gels, Catalysts and Zeolites; Foundries in the production
of molds, etc.; Soil Stabilization; Silica Sols, Water Treatment, and
Coatings. |